A Practical Approach for the Calculation of the Activation Energy of the Sintering

Authors

  • Vaclav Pouchly CEITEC BUT, Brno University of Technology
  • Jan Hruby CEITEC BUT, Brno University of Technology
  • Karel Maca CEITEC BUT, Brno University of Technology

Abstract

Newly developed software for calculation of activation energy (Qs in the following) of sintering using the Wang and Raj model is presented. To demonstrate the practical potential of the software and to evaluate the behaviour of the Qs during the sintering process, alumina and cubic zirconia ceramic compacts were prepared from nanometric powders. The results obtained with both materials are in agreement with previously published data calculated by different approaches. In the interval of interest (relative densities from 60 % to almost 100 % of theoretical density), both materials show similar behaviour. Three distinct regions can be seen: the initial constant values of Qs 868 kJ/mol and 762 kJ/mol for alumina and cubic zirconia, respectively; a region containing linear drop of Qs and the final region of constant Qs values 625 kJ/mol and 645 kJ/mol for alumina and cubic zirconia, respectively.

Downloads

Published

2017-12-13

Issue

Vol. 48 No. 3 (2016)

Section

Articles

License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Authors retain copyright of the published papers and grant to the publisher the right to publish the article, to be cited as its original publisher in case of reuse, and to distribute it in all forms and media. Articles will be distributed under the Creative Commons Attribution International License (CC BY 4.0).